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(Solution) - The kinetics of acetone hydrogenation on Pt

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The kinetics of acetone hydrogenation on Pt catalysts has been studied by Sen and Vannice (See Problem 7.9) [35]. To determine which bonding mode is more probable, the heat of adsorption for an on-top ?1 ?2 adsorbed acetone species was compared to that for a di-s-bonded ?2 ?2 species which had a C atom and the O atom interacting with a close-packed Pt (111) surface. What are these two values? Which species is favored?


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This question was answered on: Jul 11, 2017

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